| 侧链含8-羟基喹啉铝配合物的聚苯乙烯的合成与发光性能研究 |
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| 引用本文： | 张伟,高保娇,陈迎鑫. 侧链含8-羟基喹啉铝配合物的聚苯乙烯的合成与发光性能研究[J]. 高分子学报, 2011, 0(12): 1382-1389 |
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| 作者姓名： | 张伟 高保娇 陈迎鑫 |
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| 作者单位： | 中北大学化学工程系; |
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| 基金项目： | 山西省自然科学基金(基金号201002100843)资助项目 |
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| 摘 要： | 通过高分子反应法研究制备了高分子化的8-羟基喹啉铝发光材料.首先使用自制的氯甲基化试剂1,4-二氯甲氧基丁烷(BCMB),制备了5-氯甲基-8-羟基喹啉(CHQ)；通过聚苯乙烯(PS)与CHQ之间的Friedel-Crafts烷基化反应,制得侧链键合有8-羟基喹啉(HQ)的改性聚苯乙烯HQ-PS；再使HQ-PS与二配体...
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| 关 键 词： | 8-羟基喹啉铝 聚苯乙烯 Friedel-Crafts烷基化反应 荧光发射 |
SYNTHESIS OF POLYSTYRENE WITH 8-HYDROXYQUINOLINE ALUMINUM COMPLEX-CONTAINING SIDE CHAINS AND ITS LUMINOUS PERFORMANCE |
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| ZHANG Wei,GAO Baojiao,CHEN Yingxin. SYNTHESIS OF POLYSTYRENE WITH 8-HYDROXYQUINOLINE ALUMINUM COMPLEX-CONTAINING SIDE CHAINS AND ITS LUMINOUS PERFORMANCE[J]. Acta Polymerica Sinica, 2011, 0(12): 1382-1389 |
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| Authors: | ZHANG Wei GAO Baojiao CHEN Yingxin |
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| Affiliation: | ZHANG Wei,GAO Baojiao,CHEN Yingxin(Department of Chemical Engineering,North University of China,Taiyuan 030051) |
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| Abstract: | 5-Chloromethyl-8-hydroxyquinoline(CHQ) was first prepared through the reaction between HQ and chloromethylation reagent 1,4-bichloromethoxy-butane(BCMB).The Friedel-Crafts alkylation reaction was carried out between CHQ and polystyrene(PS),and HQ was bounded onto the side chains of PS,obtaining the modified polystyrene HQ-PS.And then,the coordination reaction between HQ-PS and 8-hydroxyquinoline aluminum complex Alq2 that have two HQ ligands was conducted,and the luminous material Alq3-PS,on which 8-hydroxy... |
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| Keywords: | 8-Hydroxyquinoline aluminum Polystyrene Friedel-Crafts alkylation reaction Fluorescence-emission |
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