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Preparation of micron-sized nonspherical polystyrene/poly(styrene-co-ethyleneglycol dimethacrylate) particles by seeded soap-free emulsion polymerization
Authors:Ze-feng Wang  Tao Wang  Li-na Bian  Li-min Zhou  Shan Shi  Shin-ichi Kuroda
Affiliation:Ze-feng Wang~a,Tao Wang~a,Li-na Bian~a,Li-min Zhou~b,Shan Shi~(a**) and Shin-ichi Kuroda~b a Key Laboratory of Applied Technology of Polymer Materials,College of Materials Science and Engineering,Shenyang University of Chemical Technology,Shenyang 110142,China b Department of Production Science and Technology,Faculty of Engineering,Gunma University,Ota 373-0057,Japan
Abstract:Micron-sized nonspherical polymer particles having different morphologies were synthesized by seeded soap-free emulsion polymerization of styrene(St) and ethyleneglycol dimethacrylate(EGDMA,used as a crosslinker) on spherical, linear polystyrene(PS) seed particles.The morphology of the resulting PS/poly(St-co-EGDMA) particles was dependent on the crosslinker concentration and polymerization temperature.
Keywords:Nonspherical  Polymer particles  Seeded soap-free emulsion polymerization  Crosslinking.  
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