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Microdomain morphology of cylinder-forming diblock copolymers under spherical shell confinement
Authors:Ai-hua Chai  Lin-xi Zhang
Institution:Ai-hua Chai~(a,c) and Lin-xi Zhang~(b**) a Department of Physics,Zhejiang University,Hangzhou 310027,China b Department of Physics,Wenzhou University,Wenzhou 325027,China c College of Mathematics,Physics and Information Engineering,Jiaxing University,Jiaxing 314000,China
Abstract:The topic of self-assembly of cylinder-forming diblock copolymers(DBCPs) under spherical shell confinement in different surface fields is explored using real-space self-consistent field theory calculations(SCFT).Using this approach we observed various microstructures of cylinder-forming DBCPs at different confinement dimensions and surface fields.From detailed searching for the microdomain morphologies,an obvious conclusion is that the interactions between the confinement surface and the polymers have a gre...
Keywords:Diblock copolymer  Self-assembly  Self-consistent-field theory  
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