| 开环易位聚合聚双环戊二烯的合成及结构与性能的研究进展 |
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| 引用本文： | 胡方圆,郑玉斌.开环易位聚合聚双环戊二烯的合成及结构与性能的研究进展[J].高分子通报,2011(9):139-150. |
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| 作者姓名： | 胡方圆 郑玉斌 |
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| 作者单位： | 大连理工大学化工学院高分子材料系辽宁省高分子科学与工程重点实验室,大连,116024 |
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| 摘 要： | 开环易位聚合环烯烃已成为高分子工程领域的一个研究热点。其中，由于双环戊二烯（DCPD）价格低廉、来源充分、聚合后形成的聚双环戊二烯（PDCPD）具有优异的力学性能等优点，使得DCPD的开环易位聚合得到广泛关注。本文综述了DCPD开环易位聚合反应机理、催化体系、PDCPD的结构、PDCPD的表面改性、纳米共聚物以及PDC...
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| 关 键 词： | 双环戊二烯 开环易位聚合 聚合机理 催化体系 聚双环戊二烯 |
Advance in Research of ROMP of DCPD and the Structures and Applications of PDCPD |
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| HU Fang-yuan,ZHENG Yu-bin.Advance in Research of ROMP of DCPD and the Structures and Applications of PDCPD[J].Polymer Bulletin,2011(9):139-150. |
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| Authors: | HU Fang-yuan ZHENG Yu-bin |
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| Institution: | HU Fang-yuan,ZHENG Yu-bin*(Liaoning Province Key Laboratory of Polymer Science and Engineering,Department of Polymer Science and Engineering,School of Chemical Engineering,Dalian University of Technology,Dalian 116024,China) |
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| Abstract: | Ring-opening metathesis polymerization(ROMP) of cycloolefins has become a research hotspot,among which the ROMP of dicyclopentadiene(DCPD) gains widespread interest recently due to the low cost,sufficient source and the excellent mechanical properties of polydicyclopentadiene(PDCPD).The mechanism of ROMP,the catalysts used in the ROMP of DCPD and the chemical structures of PDCPD were introduced,advances in PDCPD materials,the surface modification of PDCPD,PDCPD nanocopolymers and PDCPD self-healing(assembli... |
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| Keywords: | DCPD ROMP Polymerization mechanism Catalyst system PDCPD |
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