| Mn4-硫杂杯[4]芳烃单元的溶剂导向超分子组装 |
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| 引用本文： | 毕研峰,廖伍平. Mn4-硫杂杯[4]芳烃单元的溶剂导向超分子组装[J]. 高等学校化学学报, 2011, 32(9): 2175-2180 |
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| 作者姓名： | 毕研峰 廖伍平 |
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| 作者单位： | 中国科学院长春应用化学研究所, 稀土资源利用国家重点实验室, 长春 130022 |
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| 基金项目： | 国家自然科学基金(批准号:20971119)资助 |
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| 摘 要： | 以去叔丁基硫杂杯[4]芳烃与Mn(II)为研究对象，通过改变体系溶剂分别得到了两个四核化合物Mn4(T4A)2 (1)和Mn4(T4A)2(DMF)2(2) (T4A = thiacalix[4]arene)。当反应溶剂为氯仿(CHCl3)和甲醇的混合溶剂时，形成的是以四核锰为结构单元的二维“笼目”(Kagomé)状超分子化合物1，而当反应溶剂为N,N-二甲基甲酰胺(DMF)和甲醇的混合溶剂时，得到的是格子状二维超分子互穿的三维结构化合物2。化合物1具有很大的溶剂占有空隙，是一个潜在的多孔材料，而化合物2是一个紧密堆积的拓展结构。
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| 关 键 词： | 杯芳烃 核簇 诱导作用 超分子组装 |
| 收稿时间： | 2011-05-03 |
Solvent-directing Supramolecular Assemblies of Mn_4-thiacalix[4]arene |
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| BI Yan-Feng,LIAO Wu-Ping. Solvent-directing Supramolecular Assemblies of Mn_4-thiacalix[4]arene[J]. Chemical Research In Chinese Universities, 2011, 32(9): 2175-2180 |
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| Authors: | BI Yan-Feng LIAO Wu-Ping |
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| Affiliation: | State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China |
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| Abstract: | Two tetranuclear compounds,Mn4 ( T4A ) 2 ( 1 ) and Mn4 ( T4A ) 2 ( DMF ) 2 ( 2 ) ( T4A =thiacalix [4]arene),were synthesized via the solvothermal reaction of manganese ( Ⅱ ) acetate and thiacalix [4]arene with different solvents.Single-crystal analysis reveals that compound 1 with a two-dimensional Kagomé lattice was obtained in the mixed CHCl3/CH3OH solvent,while the interpenetrated 2D compound 2 was synthesized in the mixed DMF/CH3OH solution.Porous compound 1 has some large solvent accessible voids while compound 2 has an impacted extended structure. |
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| Keywords: | Calixarene Metal cluster Inductive effect Supramolecular assembly |
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