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SYNTHETIC STUDIES ON BLOOD COMPATIBLE BIOMATERIALS Ⅲ. SYNTHESIS, CHARAC-TERIZATION AND ANTITHROMBOGENICITY OF DIMETHYLDIPHEN YLPOLYSILOXANE/POLY (OXYTETRAM ETHYLENE)-POLYUREA SEGMENTED COPOLYMERS
引用本文:林思聪,姚旭东,屠湘同,朱永,Charles L. Liotta. SYNTHETIC STUDIES ON BLOOD COMPATIBLE BIOMATERIALS Ⅲ. SYNTHESIS, CHARAC-TERIZATION AND ANTITHROMBOGENICITY OF DIMETHYLDIPHEN YLPOLYSILOXANE/POLY (OXYTETRAM ETHYLENE)-POLYUREA SEGMENTED COPOLYMERS[J]. 高分子科学, 1992, 0(2): 127-136
作者姓名:林思聪  姚旭东  屠湘同  朱永  Charles L. Liotta
作者单位:Department of Chemistry,Nanjing University,Nanjing,Department of Chemistry,Nanjing University,Nanjing,Department of Chemistry,Nanjing University,Nanjing,Department of Chemistry,Nanjing University,Nanjing,School of Chemistry,Georgia Institute of Technology,Atlanta,U.S.A.
摘    要:A novel class of segmented copolymers, dimethyldiphenylpolysiloxane/poly (oxytetramethylene)-polyurea (PSPEU), was synthesized from α, ω-bis (γ-aminopropyl) dimethyldiphenylpolysiloxane (APMPS), which was prepared by means of basic ring-opening copolymerization of octamethylcyclotetrasiloxane, hexaphenylcyclotrisiloxane and 1, 3-bis (γ-aminopropyl) tetramethyl disiloxane. The relationships between the diphenylsiloxy contents and the properties of APMPS, including refractive index, glass transition temperature, solubility parameter as well as thermal stability, were investigated; meanwhile, the thermal stability, dynamic mechanical properties, mechanical properiesas well as the antithrombogenicity in vitro of the PSPEU were also revealed.

收稿时间:1991-03-25

SYNTHETIC STUDIES ON BLOOD COMPATIBLE BIOMATERIALS Ⅲ. SYNTHESIS, CHARAC-TERIZATION AND ANTITHROMBOGENICITY OF DIMETHYLDIPHEN YLPOLYSILOXANE/POLY (OXYTETRAM ETHYLENE)-POLYUREA SEGMENTED COPOLYMERS
LIN Sicong YAO Xudong TU Xiangton and ZHU Yong. SYNTHETIC STUDIES ON BLOOD COMPATIBLE BIOMATERIALS Ⅲ. SYNTHESIS, CHARAC-TERIZATION AND ANTITHROMBOGENICITY OF DIMETHYLDIPHEN YLPOLYSILOXANE/POLY (OXYTETRAM ETHYLENE)-POLYUREA SEGMENTED COPOLYMERS[J]. Chinese Journal of Polymer Science, 1992, 0(2): 127-136
Authors:LIN Sicong YAO Xudong TU Xiangton and ZHU Yong
Affiliation:Department of Chemistry; Nanjing University; Nanjing; School of Chemistry; Georgia Institute of Technology; Atlanta; U.S.A.
Abstract: A novel class of segmented copolymers, dimethyldiphenylpolysiloxane/poly (oxytetramethylene)-polyurea (PSPEU), was synthesized from α , ω-bis (γ-aminopropyl) dimethyldiphenylpolysiloxane (APMPS), which was prepared by means of basic ring-opening copolymerization of octamethylcyclotetrasiloxane, hexaphenylcyclotrisiloxane and 1, 3-bis (γ-aminopropyl) tetramethyl disiloxane. The relationships between the diphenylsiloxy contents and the properties of APMPS, including refractive index, glass transition temperature,solubility parameter as well as thermal stability,were investigated;meanwhile,the thermal stability,dynamic mechanical properties,mechanical properies as well as the antithrombogenicity in vitro of the PSPEU were also revealed.
Keywords:Antithrombogenicity: Blood compatible biomaterials  Segmented copolymers  Silicone rubber  Polyurethane rubber
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