| Cobalt(II) Salen Complex with Two Aza-crown Pendants and Its Analogues as Synthetic Oxygen Carriers |
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| 作者姓名： | 魏星跃 李建章 毛治华 周波 秦圣英 |
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| 作者单位： | Department of Chemistry，Sichuan University，Chengdu，Sichuan 610064，China，Department of Chemistry，Sichuan University，Chengdu，Sichuan 610064，China，Analytical and Testing Center，Sichuan University，Chengdu，Sichuan 610064，China，Department of Chemistry，Sichuan University，Chengdu，Sichuan 610064，China，Department of Chemistry，Sichuan University，Chengdu，Sichuan 610064，China |
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| 基金项目： | Project supported by the National Natural Science Foundation of China (Nos. 29572050 and 20072025). |
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| 摘 要： | Introduction Synthetic oxygen carriers1 are of great interest as models to mimic oxygen carrying metalloenzymes2 for oxygen storage and transport. The cobalt(II) complexes of Schiff bases, such as Salen and its analogues, have been the first and the most extensively investigated due to their structural similarity to those found in biological systems.3,4 However, these complexes are easy to dimerize and lose activities after oxygen molecule ab-sorption.5 Avdeef and coworkers6 demonstrated tha…
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Cobalt(II) Salen Complex with Two Aza-crown Pendants and Its Analogues as Synthetic Oxygen Carriers |
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| WEI,Xing-Yuea LI,Jian-Zhanga MAO,Zhi-Huab ZHOU,Boa QIN,Sheng-Ying,a a.Cobalt(II) Salen Complex with Two Aza-crown Pendants and Its Analogues as Synthetic Oxygen Carriers[J].Chinese Journal of Chemistry,2004(6). |
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| Authors: | WEI Xing-Yuea LI Jian-Zhanga MAO Zhi-Huab ZHOU Boa QIN Sheng-Ying a a |
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| Institution: | WEI,Xing-Yuea LI,Jian-Zhanga MAO,Zhi-Huab ZHOU,Boa QIN,Sheng-Ying*,a a Department of Chemistry,Sichuan University,Chengdu,Sichuan 610064,China b Analytical and Testing Center,Sichuan University,Chengdu,Sichuan 610064,China |
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| Abstract: | |
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| Keywords: | benzo-10-aza-15-crown-5 bis-Schiff base transition-metal complex synthesis oxygenation alkali metal ion |
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