Abstract: | 2-Nitraminopyrimidine and its 5-R derivatives (R=Me, Cl, NO2, Ph, p-O2NC6H4) have been prepared by cyclization of nitroguanidine with 2-methyl-3-dimethylaminoacrolein or bis(dimethylamino)trimethinium salts, and also by nitration of the corresponding aminopyrimidines. By interaction of these nitramino derivatives with hydroxylamine, substituted 2-hydroxyaminopyrimidines have been obtained.Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk 630090. Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 7, pp. 962–966, July, 1997. |