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Polymers based on anionic octahedral cluster chalcocyanohydroxorhenium complexes and cations [Cu(En)2]2+ |
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| Authors: | A V Ermolaev A I Smolentsev Yu V Mironov |
| Institution: | 1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, r. akademika Lavrent’eva 3, Novosibirsk, 630090, Russia 2. Novosibirsk State University, Pirogova str. 2, Novosibirsk, 630090, Russia |
| Abstract: | Polymer compounds Cu(En)2(H2O)2]{Cu(En)2}Re6S8(CN)4(OH)2] · 5.5H2O (I) and Cu(En)2(H2O)2]{Cu(En)2}Re6Se8(CN)4(OH)2] · 5H2O (II) are synthesized by the layering of an ammonia solution of CuCl2 with ethylenediamine (En) on aqueous solutions of the corresponding octahedral cluster chalcocyanohydroxorhenium complexes. The compounds are characterized by IR spectroscopy and elemental and X-ray diffraction analyses. |
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