Transmetalation of (octaphenyltetraazaporphyrinato)magnesium(II) with manganese(II) chloride in dimethylformamide |
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| Authors: | S. V. Zvezdina N. V. Chizhova N. Zh. Mamardashvili |
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| Affiliation: | 1. Krestov Institute of Solution Chemistry, Russian Academy of Sciences, ul. Akademicheskaya 1, Ivanovo, 153040, Russia
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| Abstract: | The reaction of (octaphenyltetraazaporphyrinato)magnesium(II) with manganese(II) chloride in dimethylformamide gave (chloro)(octaphenyltetraazaporphyrinato)manganese(III). Reactions of the latter with nitrogen-containing bases were studied. The kinetic parameters of the transmetalation of (octaphenyltetraazaporphyrinato) magnesium(II) with MnCl2 in dimethylformamide at 323, 333, and 343 K were determined, and a probable reaction mechanism was proposed. |
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