Preparation of non-valence compounds of zinc(II) with 1,2- and 1,4-benzenedicarboxylic acids via self-assembly |
| |
| Authors: | B T Usubaliev A L Shabanov A Sh Tomueva M K Munshieva P S Safarova F B Alieva Z A Mamedova |
| |
| Institution: | 1. Scientific Research Institute “Geotechnology Problems of Oil, Gas, and Chemistry,”, Azerbaijan State Oil Academy, ul. D. Alieva 227, Baku, 1010, Azerbaijan
2. M.F. Nagiev Institute of Chemical Problems, National Academy of Sciences of Azerbaijan, Baku, Azerbaijan
|
| |
| Abstract: | Nanostructured non-valence compounds based on coordination compounds of zinc(II) with phthalic and terephthalic acids have been prepared. The purity and composition of prepared compounds have been elucidated from X-ray diffraction analysis, IR spectroscopy, elemental analysis, and thermogravimetry studies; thermal decomposition of the non-valence compounds has been studied as well. The prepared self-assembled compounds are co-precipitated with one water molecule and 1.5 acetic acid molecules per unit of the dicarboxylic acid: Zn4(OH)6·o-C6H4(COO)2]·H2O·1.5CH3COOH and Zn4(OH)6·p-C6H4(COO)2]·H2O· 1.5CH3COOH. |
| |
| Keywords: | |
| 本文献已被 SpringerLink 等数据库收录！ |
|
