A novel Cd(II) complex with 1,3-bis(4-Pyridyl)propane: Synthesis,crystal structure,and interaction with DNA |
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| Authors: | E. J. Gao X. Y. Xu M. C. Zhu H. L. Yan H. Fu H. Wang L. Zhan Q. Yao M. Y. Li M. P. Jiang |
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| Affiliation: | 1. Laboratory of Coordination Chemistry, Shenyang University of Chemical Technology, Shenyang, 110142, P.R. China
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| Abstract: | The complex [Cd(Bpp)3Cl2] n · 2H2O (Bpp = 1,3-bis(4-pyridyl)propane) has been synthesized and characterized by elementary analysis, IR spectrum and singel-crystal X-ray diffraction. The crystal belongs to monoclinic system, space group C2/c with the crystal cell parameters of a = 31.05(3), b = 17.556(13), c = 16.281(13) Åβ = 121.402(7)°, V = 7574(10) Å3, and Z = 8. The compound has formed a 1D surface shape structure through these coordinate modes with the ligand. The 2D layers are further aggregated by hydrogen bonding with octameric subunits. |
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