| 大分子偶联剂马来酸酐-丙烯酸丁酯-苯乙烯三元共聚物的合成及其对纳米氮化铝的表面改性 |
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| 引用本文： | 乔恒婷,夏茹,章于川. 大分子偶联剂马来酸酐-丙烯酸丁酯-苯乙烯三元共聚物的合成及其对纳米氮化铝的表面改性[J]. 应用化学, 2010, 27(1): 16-20 |
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| 作者姓名： | 乔恒婷 夏茹 章于川 |
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| 作者单位： | (安徽大学化学化工学院，安徽省绿色高分子重点实验室 合肥 230039) |
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| 基金项目： | 国家科技攻关计划，安徽省高等学校青年教师科研项目 |
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| 摘 要： | 采用自由基溶液聚合法合成了马来酸酐（MAn）-丙烯酸丁酯（BA）-苯乙烯（St）三元共聚物大分子偶联剂，并用其对纳米氮化铝（AlN）粉体进行了表面改性。通过GPC、FTIR、沉降实验、TGA、接触角以及TEM的分析表明，合成的大分子偶联剂，数均相对分子量在3 000~10 000之间，适于对纳米粉体进行包覆；单体投料摩尔比为１:１:５的MAn-BA-St三元共聚物大分子偶联剂对纳米AlN的改性效果最好，其化学利用率为52.5%，物理利用率为25%；改性后纳米AlN的表面自由能从879 J/M2降至221 J/M2，在苯乙烯中分散良好。
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| 关 键 词： | 三元共聚物，纳米氮化铝，不饱和聚酯，表面改性 |
| 收稿时间： | 2009-01-07 |
| 修稿时间： | 2009-04-10 |
Synthesis of Tercopolymer MAn-BA-St and Its Surface Modification for Nano-AlN with this Macromolecular Coupling Agent |
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| QIAO Heng-Ting,XIA Ru,ZHANG Yu-Chuan. Synthesis of Tercopolymer MAn-BA-St and Its Surface Modification for Nano-AlN with this Macromolecular Coupling Agent[J]. Chinese Journal of Applied Chemistry, 2010, 27(1): 16-20 |
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| Authors: | QIAO Heng-Ting XIA Ru ZHANG Yu-Chuan |
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| Affiliation: | (School of Chemistry and Chemical Engineering,Anhui University,Anhui Key Laboratory of ;Enviroment-friendly Polymer Materials,Hefei 230039) |
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| Abstract: | A new macromolecular coupling agent,maleic anhydride(MAn)-butyl acrylate(BA)-styrene(St) tercopolymer,was synthesized via solution free radical polymerization and used to modify aluminum nitride(AIN).The molecular structure of the terpolymer was confirmed by FTIR,and its average molecular mass was determined by GPC.The structure,surface properties and thermal stability of the modified nano-AlN were systematically investigated by FTIR,contact angle,TGA,TEM and sedimentation experiment.The results show that t... |
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| Keywords: | tercopolymer nanosized aluminum nitride(AlN) unsaturated polyester resin surface modification |
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