Electrocatalytic multicomponent cyclization of aromatic aldehydes,malononitrile, and malonates into 3-substituted 2,2-dicyanocyclopropane-1,1-dicarboxylates |
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Authors: | A. N. Vereshchagin M. N. Elinson A. S. Dorofeev G. I. Nikishin |
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Affiliation: | (1) Department of Chemistry, McGill University, Montreal, QC, Canada; |
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Abstract: | Electrolysis of aromatic aldehydes, malononitrile and malonates in methanol in an undivided cell in the presence of double-mediator system NaBr-NaOAc afforded 3-substituted 2,2-dicyanocyclopropane-1,1-dicarboxylates in 40–60% yields. |
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