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Electrocatalytic multicomponent cyclization of aromatic aldehydes,malononitrile, and malonates into 3-substituted 2,2-dicyanocyclopropane-1,1-dicarboxylates
Authors:A N Vereshchagin  M N Elinson  A S Dorofeev  G I Nikishin
Institution:(1) Department of Chemistry, McGill University, Montreal, QC, Canada;
Abstract:Electrolysis of aromatic aldehydes, malononitrile and malonates in methanol in an undivided cell in the presence of double-mediator system NaBr-NaOAc afforded 3-substituted 2,2-dicyanocyclopropane-1,1-dicarboxylates in 40–60% yields.
Keywords:
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