2-Carbamoylaziridine (Leakadine): diastereoselective transformations and stereoelectronic effect* |
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Authors: | R. G. Kostyanovsky G. K. Kadorkina O. N. Krutius I. I. Chervin |
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Affiliation: | 1. N. N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, 4 Kosygina St., Moscow, 119991, Russia
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Abstract: | Diastereoselective transformations of Leakadine were discovered: dimerization during melting or heating in CHCl3 with the formation of one diastereomer. The obtained dimer reacts with methyl isocyanate under mild conditions with the formation of an N-methylcarbamoyl derivative – also in the form of one diastereomer. In the diastereoselective reaction of Leakadine with dimethyl formamide dimethyl acetal, 2-dimethylamino-1,3-diazabicyclo[3.1.0]hexan-4-one was obtained. The reaction of Leakadine with perfluoroisobutylene was studied. |
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