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Photo-induced catalytic partial oxidation of citronellol with assistance of phthalocyanines |
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| Authors: | Petr Kluson Martin Drobek Tomas Strasak Ali Kalaji |
| Affiliation: | (1) Faculty of Chemical Technology, Institute of Chemical Technology — ICT Prague, Technicka 5, 166 28 Prague, Czech Republic;(2) Institute of Chemical Process Fundamentals, Academy of Sciences of the Czech Republic, Rozvojova 135, 165 02 Prague, Czech Republic;(3) School of Chemistry, University of Southampton, University Road, Southampton, SO17 1BJ, UK |
| Abstract: | Attention was paid to the role of sulfonated phthalocyanines as efficient photocatalysts in the photo-induced partial oxidation of citronellol. Performance of the singlet oxygen species inducing the formation of citronellol hydroperoxides was studied in detail. The involved reactions may be of great importance in the catalytic production of rose oxide — a highly appreciated component of many synthetic fragrances. |
| Keywords: | Photooxidation phthalocyanine citronellol quantum yield photocatalysis |
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