Alkoxy-, acyloxy-, and bromomethylation of resorcinarenes |
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| Authors: | Nummelin Sami Falabu Deszö Shivanyuk Alexander Rissanen Kari |
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| Institution: | Nanoscience Center, Department of Chemistry, University of Jyv?skyl?, P.O. Box 35, FIN-40351, Jyv?skyl?, Finland. |
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| Abstract: | Reaction of resorcinarene octols with tris-hydroxymethylmethylamine (TRIS), formaldehyde, and alcohols results in tetraalkoxymethylation of the resorcinol rings. Harsh acylation of aminomethylated resorcinarenes with acid anhydrides leads to the complete acylation of eight hydroxyls and substitution of the amino versus acyloxy groups. Acyloxymethylated resorcinarene 6b can be transformed into a tetrabromomethylated derivative 7 through the reaction with HBr in acetic acid. |
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