Intermolecular radical carboaminohydroxylation of olefins with aryl diazonium salts and TEMPO |
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| Authors: | Heinrich Markus R Wetzel Alexander Kirschstein Marcel |
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| Affiliation: | Lehrstuhl für Organische Chemie 1, Technische Universit?t München, Lichtenbergstrasse 4, D-85747 Garching, Germany. markus.heinrich@ch.tum.de |
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| Abstract: | Highly reactive aryl radicals can selectively be reacted with a broad variety of activated and nonactivated olefinic substrates in the presence of nitroxyl radicals. Direct recombination of the aryl radical and the nitroxide as well as telomerization of the olefin is successfully suppressed by the reaction conditions. |
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