Reduced Overlap Population Analysis for Triosmium Clusters |
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| Authors: | Elizabeth C. Morrison Weng Kee Leong Jialin Tan |
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| Affiliation: | (1) School of Education and Training, University of Greenwich, Mansion Site, Bexley Road, Eltham, London, SE9 2PQ, UK;(2) Department of Chemistry, National University of Singapore, Kent Ridge, Singapore, 119260, Singapore |
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| Abstract: | The use of reduced overlap population (ROP) analysis from EHMO calculations as a means to gauge the presence of metal–metal bonds in triosmium clusters is examined. A number of triosmium clusters containing bridging ligands have been used as test cases, including the bis-ethoxy bridged cluster Os3(μ-OEt)2(CO)10, 1b, and some of its group 15 derivatives Os3(μ-OEt)2(CO)9(EPh3), 2. These latter clusters are newly synthesized and have been characterized completely, including by single-crystal X-ray crystallographic studies. In honour of Professor Dieter Fenske on his 65th birthday. |
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| Keywords: | EHMO ROP osmium cluster alkoxy |
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