| Recent Advances in Organic Reactions Catalyzed by Lanthanide（Ⅲ） Complexes |
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| 引用本文： | 陈瑞芳,钱长涛.Recent Advances in Organic Reactions Catalyzed by Lanthanide（Ⅲ） Complexes[J].中国化学,2002,20(5):407-419. |
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| 作者姓名： | 陈瑞芳 钱长涛 |
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| 作者单位： | [1]StateKeyLaboratoryofOrganometallicChemistry,ShanghaiInstituteofOrganicChemistry,ChineseAcademyofSciences,Shanghai200032,China [2]StateKeyLaboratoryofOrganometallicChemistry,ShanghaiInstituteofOrganicChem |
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| 摘 要： | Lanthanide compounds have been attracting much attention in organic synthesis.Chiral Ln-substituted BINOL have been widely studied in several asymmetric organic reactions.LnCl3 and Ln(OTf)3 have been expected to serve as Lewis acide and have been applied to many important synthetic reactions in a one-pot manner,Ln(O-i-Pr)3 exhibits some basic characters,which also can be utilized in some special organic transformation.This article deals with some lanthanides(Ⅲ）complexes promoted organic reactios,which we have recently developed.
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| 关 键 词： | 氯化镧 镧（Ⅲ） 配合物 有机反应 催化剂 有机合成 |
Recent Advances in Organic Reactions Catalyzed by Lanthanide (III) Complexes |
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| Chen Rui‐Fang,Qian Chang‐Tao.Recent Advances in Organic Reactions Catalyzed by Lanthanide (III) Complexes[J].Chinese Journal of Chemistry,2002,20(5):407-419. |
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| Authors: | Chen Rui‐Fang Qian Chang‐Tao |
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| Abstract: | Lanthanide compounds have been attracting much attention in organic synthesis. Chiral Ln‐substituted BINOL have been widely studied in several asymmetric organic reactions. LnCl3 and Ln(OTf)3 have been expected to serve as Lewis acids and have been applied to many important synthetic reactions in a one‐pot manner. Ln(O‐i‐Pr)3 exhibits some basic characters, which also can be utilized in some special organic transformation. This article deals with some lanthanides(III) complexes promoted organic reactions, which we have recently developed. |
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| Keywords: | lanthanide chiral Ln‐BINOL LnCl3 Ln(OTf)3 organic reaction |
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