Thermodynamic Studies as Predictive Tools of the Behavior of Electroceramics Under Different Hydrothermal Environments |
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Authors: | Anderson Dias |
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Institution: | (1) Departamento de Química, Universidade Federal de Ouro Preto, ICEB II, Sala 67, Ouro Preto-MG, 35400-000, Brazil |
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Abstract: | Thermodynamic simulations are performed in all areas of materials processing because of the advances that have taken place
in computer software for complex non-ideal calculations, together with the increasing availability of evaluated data for different
phases. In the present work, a thermodynamic model of electrolytic solutions was applied to determine the reaction conditions
favoring the hydrothermal synthesis of the following electroceramics: zinc ferrites, sodium niobates, and lead zirconates.
Stability and yield diagrams were constructed relating the equilibrium concentration of all of the aqueous and solid species
as functions of temperature, pressure, pH, and input reagent concentrations. The theoretical predictions avoided the empirical
trial-and-error method of synthesis and were corroborated by experiments. The results demonstrate the important role that
such thermodynamic simulations can play in significantly reducing the time and costs associated with hydrothermal processing. |
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Keywords: | Thermodynamics Hydrothermal synthesis Microwave Ferrites Perovskites Niobates Zirconates |
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