Thermokinetics of the reaction of phenyl glycidyl ether with aniline |
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| Authors: | R. M. Vinnik E. A. Miroshnichenko V. A. Roznyatovsky |
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| Affiliation: | (1) N. N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, 4 ul. Kosygina, 119991 Moscow, Russian Federation;(2) Department of Chemistry, M. V. Lomonosov Moscow State University, 1 Leninskie Gory, 119992 Moscow, Russian Federation |
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| Abstract: | The thermokinetic curves in the reaction of phenyl glycidyl ether with aniline were calculated for various compositions of the reaction mixture and temperatures. In addition to the main exothermic effect related to the epoxide ring opening, another exothermic effect of unknown nature was observed. The kinetic data obtained are explained in terms of structural changes caused by the self-aggregation of the reaction product molecules. The “kinetic investigation” approach provides a quantitative analysis of calorimetric data.__________Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 371–375, February, 2005 |
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| Keywords: | “ kinetic investigation” approach thermokinetics phenyl glycidyl ether thermochemistry epoxy compounds self aggregation |
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