Metal-dependent regioselective oxidative coupling of 5,10,15-triarylporphyrins with DDQ-Sc(OTf)3 and formation of an oxo-quinoidal porphyrin |
| |
| Authors: | Kamo Makoto Tsuda Akihiko Nakamura Yasuyuki Aratani Naoki Furukawa Ko Kato Tatsuhisa Osuka Atsuhiro |
| |
| Affiliation: | Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo-ku, Kyoto 606-8502, Japan. |
| |
| Abstract: | [reaction: see text] Regioselectivity of the oxidative coupling of 5,10,15-triarylporphyrin metal complexes with DDQ-Sc(OTf)(3) was dependent on the central metal and meso-aryl substituent. Oxo-quinoidal porphyrin was obtained from Ni(II) porphyrin under the same conditions. |
| |
| Keywords: | |
| 本文献已被 PubMed 等数据库收录！ |
|
