Bhc-diol as a photolabile protecting group for aldehydes and ketones |
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| Authors: | Lu Min Fedoryak Olesya D Moister Brent R Dore Timothy M |
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| Institution: | Department of Chemistry, University of Georgia, Athens, Georgia 30602-2556, USA. |
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| Abstract: | reaction: see text] 6-Bromo-4-(1,2-dihydroxyethyl)-7-hydroxycoumarin (Bhc-diol) can be used under simulated physiological conditions as a photoremovable protecting group for aldehydes and ketones. The single- and two-photon-induced release of benzaldehyde, piperonal, acetophenone, and cyclohexanone is demonstrated. |
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