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Photochromic radical compounds based on a naphthopyran system
Authors:Kaneko Takashi  Akutsu Hiroki  Yamada Jun-Ichi  Nakatsuji Shin'ichi
Affiliation:Department of Material Science, Graduate School of Science, Himeji Institute of Technology, 3-2-1 Kouto, Kamigori, Hyogo 678-1297, Japan.
Abstract:[reaction: see text] Naphthopyran derivatives with aminoxyl substituents (4a,b) gave the corresponding open-formed isomers (5a,b) by irradiation, which could be changed back to the starting closed-formed naphthopyrans by the treatment with SiO(2) as a catalyst. The tuning of intermolecular magnetic interactions between the isomer couples was found to be possible in these reversible systems.
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