Photochromic radical compounds based on a naphthopyran system |
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Authors: | Kaneko Takashi Akutsu Hiroki Yamada Jun-Ichi Nakatsuji Shin'ichi |
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Affiliation: | Department of Material Science, Graduate School of Science, Himeji Institute of Technology, 3-2-1 Kouto, Kamigori, Hyogo 678-1297, Japan. |
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Abstract: | [reaction: see text] Naphthopyran derivatives with aminoxyl substituents (4a,b) gave the corresponding open-formed isomers (5a,b) by irradiation, which could be changed back to the starting closed-formed naphthopyrans by the treatment with SiO(2) as a catalyst. The tuning of intermolecular magnetic interactions between the isomer couples was found to be possible in these reversible systems. |
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