Highly enantioselective oxidation of sulfides to sulfoxides by a new oxaziridinium salt |
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| Authors: | del Río R E Wang B Achab S Bohé L |
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| Institution: | Institut de Chimie des Substances Naturelles, CNRS, Avenue de la Terrasse, 91198 Gif sur Yvette, France. |
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| Abstract: | The new oxaziridinium salt 5 (R2 = TBDPS) is an effective reagent for the highly enantioselective oxidation of sulfides to sulfoxides with up to >99% ee and good yields. As such, it represents a new valuable nonmetallic alternative to the existing methods for asymmetric sulfoxidation. |
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