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Arylation of adamantanamines: V. Palladium-catalyzed amination of isomeric chloroquinolines with diamines of the adamantane series |
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| Authors: | O K Grigorova A D Averin A S Abel O A Maloshitskaya G M Butov E N Savelyev B S Orlinson I A Novakov I P Beletskaya |
| Institution: | 1. Faculty of Chemistry, Moscow State University, Leninskie gory 1-3, Moscow, 119991, Russia 2. Volzhsky Polytechnical Institute, ul. Engel’sa 42a, Volzhsky, Volgograd oblast, 404121, Russia 3. Volgograd State Technical University, pr. Lenina 28, Volgograd, 400005, Russia |
| Abstract: | Palladium-catalyzed arylation of diamines of the adamantane series with isomeric 2-, 4-, and 6-chloroquinoline was studied, and optimal conditions for the synthesis of the corresponding N,N′-diaryl derivatives were found. N,N-Diarylation products of primary amino groups in the diamines bearing 2-aminoethyl and 4-aminophenyl substituents were readily formed. |
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