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Photoisomerization of the Graft Copolymer of Starch and Azo-dye
Authors:FU ZhengSheng  Yang Aimei  LIANG WeiDong  WANG ZhiGuo
Abstract:Optical data storage materials are mainly based on organic molecules. To be suited for as an optical data storage material, molecules have to be photochromatic, they must be capable of being reversibly switched be. tween two spectroscopically distinct forms by use of light1].Photoisome rization (trans ~cis) of azoaromatic compounds has been investigated extensively using UV-Vis spectroscopy. In 19722], the isomerization of various azobenzenes bound on the side chain or within the main chain of poly (methyl methacrylate), poly(ethyl methacrylate),polystyrene, a polyamide, and polyester had. been demonstrated. There are three processes: a trans-cis photochemical isomerization, a cis-trans photochemical isomerization, and a cis-trans thermal isomerization, which occurs due to the higher stability of the trans configuration, since that pioneering study, two main directions of research developed and are very active in the eurrent literature.
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