Transition metal complexes of primary and secondary phosphines,part II. Some palladium(II) and platinum(II) complexes of type L3MC2 |
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| Authors: | Satya P. Anand Harold Goldwhite John R. Spielman |
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| Affiliation: | (1) Department of Chemistry, California State University, 90032 Los Angeles, California, USA |
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| Abstract: | Summary The general course of reactions between [MCl4 ]2– (M = Pd, Pt) and primary and secondary phosphines containing phenyl, cyclohexyl, or 2-cyanoethyl groups, in polar solvents, is to yield L3MCl2 complexes which are probably ionic [L3MCl]+Cl– These compounds can be isolated and characterized in the solid state, but in solution they are labile, and tend to react to give phosphines plus L2 MCI2. |
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