Iron-catalyzed synthesis of glycine derivatives via carbon-nitrogen bond cleavage using diazoacetate |
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| Authors: | Kuninobu Yoichiro Nishi Mitsumi Takai Kazuhiko |
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| Institution: | Division of Chemistry and Biochemistry, Graduate School of Natural Science and Technology, Okayama University, Tsushima, Kita-ku, Okayama 700-8530, Japan. kuninobu@cc.okayama-u.ac.jp |
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| Abstract: | Treatment of tertiary amines with diazoacetate in the presence of a catalytic amount of an iron salt, FeCl(3), in ethanol gave glycine derivatives. In this reaction, a carbon-nitrogen single bond of the amine was cleaved. |
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