M?ssbauer and other spectral studies of Fe(III) complexes of benzothiazolines |
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| Authors: | Archana Garg and J P Tandon |
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| Institution: | (1) Department of Chemistry, University of Rajasthan, 302 004 Jaipur, India |
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| Abstract: | Different molar reactions of Fe(OPr1)3, and FeCl3 with benzothiazolines having an NSH donor system. derived by the condensation ofo-aminothiophenol with heterocyclic aldehydes. viz. pyridine-2-aldehyde. furfuraldehyde and thiophene-2-aldehyde. lead to the
formation of Fe.Pr1(NS)2]2, Fc(NS)3] and Fe(NS)2Cl| type of complexes. The resulting derivatives have been characterized by elemental analysis, conductivity measurements,
molecular weight determinations and magnetic studies. IR, electronic, M?ssbauer and ESR spectral data have been used to deduce
the structures of the resulting derivatives. |
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| Keywords: | Low spin Fe (III) complexes benzothiazolines IR spectra M?ssbauer spectra ESR spectra |
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