Fabrication of polytetrafluoroethylene- and graphite-containing oxide layers on aluminum and titanium and their structure

Stable aqueous electrolyte emulsions with negatively charged micelles containing dispersed particles of polytetrafluoroethylene (PTFE) or graphite are obtained using siloxane-acrylate emulsion as an emulsifier. The oxide coatings formed in such electrolytes contain carbon, polytetrafluoroethylene, or graphite. The coatings with PTFE particles are similar to monolithic polytetrafluoroethylene with respect to its hydrophobic characteristics. According to X-ray photoelectron spectroscopy data, the surface of the formed coatings predominantly contains aliphatic carbon (C-C and C-H bonds) and some fraction of oxidized (or, in the case of PTFE-containing electrolytes, fluorinated) carbon.