Monometallic and heterobimetallic azanickellacycles as ethylene polymerization catalysts |
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| Authors: | Tanabiki Masao Tsuchiya Kazuhiro Motoyama Yukihiro Nagashima Hideo |
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| Affiliation: | TOSOH Corporation, 1-8, Kasumi, Yokkaichi, Mie, Japan. |
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| Abstract: | The azanickellacyclic complex (1) produced by trimerization of an isocyanide on the nickel atom is found to be a new ethylene polymerization catalyst; catalytic activity is increased by incorporation of the second metal to a diimino moiety of 1 leading to formation of heterobimetallic complexes. |
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