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Crystal structure of ferrocenyl amine
Authors:Cynthia?L?Perrine  Matthias?Zeller  John?Woolcock  Email author" target="_blank">Allen?D?HunterEmail author
Institution:(1) Department of Chemistry, Youngstown State University, One University Plaza, Youngstown, Ohio, 44555–3663;(2) Department of Chemistry, Indiana University of Pennsylvania, 975 Oakland Avenue, Indiana, Pennsylvania, 15705
Abstract:The title compound, ferrocenyl amine, was found to crystallize in the tetragonal space group I41/a with a = 23.5540(15), b = 5.8964(8) Å, and Z = 16. The individual molecules are interconnected by N–H⋅ < eqid1 > ⋅N bridges forming an infinite chain of hydrogen bonds in the direction of the four fold screw-axis, giving ferrocenyl amine a similar symmetry to that found for tetrameric clusters in liquid ammonia.
Keywords:Ferrocenyl amine  amines  hydrogen bonding  ammonia  infinite chain
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