| 含胺基功能性单体的聚合研究——Ⅶ.N-(4-N′,N′-二甲氨基苯基)代丙烯酰胺作为氧化还原引发体系组分的研究 |
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| 引用本文： | 李福绵,王林,冯新德.含胺基功能性单体的聚合研究——Ⅶ.N-(4-N′,N′-二甲氨基苯基)代丙烯酰胺作为氧化还原引发体系组分的研究[J].高分子学报,1984,0(3):237-240. |
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| 作者姓名： | 李福绵 王林 冯新德 |
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| 作者单位： | 北京大学化学系
(李福绵，王林)，北京大学化学系(冯新德) |
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| 摘 要： | <正> 我们曾报道过甲基丙烯酸-4-N,N-二甲氨基苄酯(DMABMA),4-N,N-二甲氨基苯乙烯(DMAS)等含芳香叔胺基的烯类衍生物不仅可以作为氧化还原引发体系组分引发烯类单体如甲基丙烯酸甲酯(MMA)的聚合,而且还进入MMA的聚合物链中。在另文中报道了两个芳香叔胺取代的丙烯酰胺:N-(4-N′,N′-二甲氨基苯基)丙烯酰胺(DMAPAA)和N-(4-N′,N′-二甲氨基苯基)甲基丙烯酰胺(DMAPMA)的合成及其聚合的研究,本文研究了这两个丙烯酰胺衍生物与过氧化苯甲酰(BPO)组成的氧化还
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| 收稿时间： | 1983-07-17 |
STUDIES ON THE POLYMERIZATION OF FUNCTIONAL MONOMERS CONTAINING AMINO-GROUPSⅦ. STUDY ON THE USE OF N-(4-N', N'-DIMETHYLAMINOPHENYL). SUBSTITUTED ACRYLAMIDES AS COMPONENT OF REDOX INITIATOR SYSTEM |
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| Li Fu-mian,Wang Lin,Feng Xin-de.STUDIES ON THE POLYMERIZATION OF FUNCTIONAL MONOMERS CONTAINING AMINO-GROUPSⅦ. STUDY ON THE USE OF N-(4-N', N'-DIMETHYLAMINOPHENYL). SUBSTITUTED ACRYLAMIDES AS COMPONENT OF REDOX INITIATOR SYSTEM[J].Acta Polymerica Sinica,1984,0(3):237-240. |
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| Authors: | Li Fu-mian Wang Lin Feng Xin-de |
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| Institution: | Department of Chemistry; Peking University |
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| Abstract: | The kinetics of the polymerization of methyl methacrylate (MMA) initiated with initiator system of benzoyl peroxide (BPO) combined with N-(4-N', N'-dimethylaminophenyl) acrylamide (DMAPAA) or N-(4N' N'-dimettylaminophenyl) methacrylamide .(DMAPMA) have been investigated. The rate equations are given asRp = Kp,DMAPAA]1/2BPO]1/2MMA] and Rp = Kp DMAPMA]1/2 BPO ]1/2 MMA],respectively. The overall activation energies of these polymerization were determined as low as 8.4 and 7.2 kcal/mol, respectively. The monomers containing teritiary amino groups not only initate the polymerization by redox nature,but also incorporate into the polymer chains. |
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