| Synthesis and Crystal Structure of a Novel 1D Chain-like Organic Inorganic Hybrid Rare Earth Derivative of Polyoxometalate: H_(0.5)[Sm(H_2O)_6]_(0.25)[Sm(H_2O)_5]_(0.25){[Sm(H_2O)_7][Sm(H_2O)_2-(DMSO)][SiW_(11)O_(39)]}·4.5H_2O |
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| 作者姓名： | Jun Wei ZHAO Jing Ping WANG Jing Yang NIU School of Chemistry and Chemical Engineering Henan University Kaifeng |
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| 作者单位： | Jun Wei ZHAO，Jing Ping WANG，Jing Yang NIU School of Chemistry and Chemical Engineering，Henan University，Kaifeng 475001 |
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| 摘 要： | Polyoxometalates may be versatile inorganic building blocks for the construction of molecular-based materials. By means of their multiple coordination requirements and oxophilicity, lanthanide cations are suitable to link polyoxometalate building blocks to form new classes of materials with potentially useful magnetic and luminescent properties1-4. Peacock and Weakley studied the interactions between the α-SiW11 O39]8? isomer and lanthanide cations5, and they reported that the α-SiW11O39…
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