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Rh(I)-catalyzed allenic Pauson-Khand reaction: first construction of the bicyclo[6.3.0]undecadienone ring system |
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| Authors: | Chisato Mukai Toshiyuki Hirose Satoshi Teramoto Shinji Kitagaki |
| Affiliation: | Division of Pharmaceutical Sciences, Graduate School of Natural Science and Technology, Kanazawa University, Kakuma-machi, Kanazawa 920-1192, Japan |
| Abstract: | The Rh(I)-catalyzed Pauson-Khand reaction of allenynes afforded the bicyclo[6.3.0]undecadienones as well as their benzo and furo derivatives. In addition, a novel [RhCl(CO)2]2-catalyzed [2,3]-sigmatropic rearrangement of the sulfinic ester species of propargyl alcohols was developed. |
| Keywords: | Pauson-Khand reaction Allenyne Bicyclo[6.3.0]undecadienone [2,3]-Sigmatropic rearrangement [RhCl(CO)2]2 [RhCl(CO)dppp]2 |
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