Imidazo[1,5-a]pyridine-3-ylidenes—pyridine derived N-heterocyclic carbene ligands |
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Authors: | Christian Burstein |
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Institution: | Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, 45470 Mülheim an der Ruhr, Germany |
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Abstract: | The ready synthesis of differently substituted 2H-imidazo1,5-a]pyridin-4-ium bromides is reported. These salts are precursors for a new class of N-heterocyclic carbene ligands. As a consequence of their bicyclic geometry, these ligands are capable of influencing the coordination sphere of a carbene bound metal. The usefulness of these ligands was demonstrated in the palladium-catalyzed Suzuki-Miyaura cross-coupling of sterically hindered aryl chlorides. |
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Keywords: | Ligand design N-heterocyclic carbene Suzuki-Miyaura cross-coupling |
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