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Horseradish peroxidase (HRP) catalyzed oxidative coupling reactions using aqueous hydrogen peroxide: an environmentally benign procedure for the synthesis of azine pigments |
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| Authors: | Anja Bodtke Norbert Ahrens |
| Affiliation: | a Institut für Chemie und Biochemie der Ernst-Moritz-Arndt-Universität Greifswald, Soldmannstr. 16, D-17487 Greifswald, Germany b Klinik für Neurologie der Ernst-Moritz-Arndt-Universität Greifswald, Ellernholzstr. 1/2, D-17487 Greifswald, Germany c Institut für Chemie, Universität Rostock, Albert-Einstein-Str. 3a, 18059 Rostock, Germany d Leibniz-Institut für Organische Katalyse an der Universität Rostock e. V. (IfOK), Albert-Einstein-Str. 29a, 18059 Rostock, Germany |
| Abstract: | The horseradish peroxidase (HRP) catalyzed oxidative coupling of 2-hydrazono-4-thiazolines with α-naphthol using aqueous hdrogen peroxide. These transformations allow an environmentally benign synthesis of p-naphthoquinone-thiazol-2-on-azines under mild conditions. |
| Keywords: | Azines Enzymatic reactions Heterocycles Oxidation Peroxidase |
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