A stereoselective synthesis of spiro-dioxolanes via the multicomponent reaction of dicarbomethoxycarbene, aldehydes and 1,2- or 1,4-diones |
| |
| Authors: | Vijay Nair Sindhu Mathai Nigam P. Rath |
| |
| Affiliation: | a Organic Chemistry Division, Regional Research Laboratory, Trivandrum 695 019, India
b Department of Chemistry, University of Missouri, St Louis, MO 63121-4499, USA |
| |
| Abstract: | The three component reaction of acyclic carbonyl ylides generated from dicarbomethoxycarbene and aldehydes with 1,2- and 1,4-diones is described. The reaction afforded the corresponding spiro-dioxolanes in good yields. |
| |
| Keywords: | Dicarbomethoxycarbene Carbonyl ylide Huisgen 1,3-dipolar cycloaddition Spiro-dioxolane |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
