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Nucleophilic addition to dimethylvinylphosphine sulfide as a convenient route to polydentate ligands containing the 2-dimethylphosphinoethyl unit
Authors:D Vaughan Griffiths  Helen J Groombridge  Stephen P Swetnam  David C York
Institution:a Department of Chemistry, Queen Mary, University of London, London E1 4NS, UK
b Department of Chemistry, University of Keele, Newcastle, Staffs ST5 5BG, UK
Abstract:The synthesis of a range of new phosphine-containing polydentate ligands has been achieved by addition of sulfur and nitrogen nucleophiles to dimethylvinylphosphine sulfide, followed by reduction of the resulting phosphine sulfides with lithium aluminium hydride.
Keywords:Phosphine  Polydentate  Ligand
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