Structures of sym-(R)dibenzo-16-crown-5-oxyacetic acids and their alkali metal cation binding |
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| Authors: | Richard A. Bartsch N. Kent Dalley David W. Purkiss |
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| Affiliation: | a Department of Chemistry and Biochemistry, Texas Tech University, Lubbock, TX 79409-1061, USA
b Department of Chemistry, Brigham Young University, Provo, UT 84602-5700, USA |
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| Abstract: | To provide insight into the influence of geminal group (R) variation in sym-(R)dibenzo-16-crown-6-oxyacetic acids upon their selectivity in alkali metal cation separations by solvent extraction and liquid membrane transport, studies have been conducted for R=hydrogen and decyl in homogeneous solutions by 1H NMR spectroscopy and titration calorimetry and in the solid state. |
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| Keywords: | Proton-ionizable lariat ethers Metal ion binding |
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