Metallation of pyridin-2-yldiazines. Use of pyridine ring as ortho-directing group. Diazines. Part 45 |
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| Authors: | Camelia Berghian Mircea Darabantu Alain Turck |
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| Institution: | a Department of Organic Chemistry, ‘Babes-Bolyai’ University, 11 Aranyi Jànos Str., RO-400028 Cluj-Napoca, Romania
b Institut de Recherche en Chimie Organique Fine (I.R.C.O.F.), Université de Rouen, BP 08, F-76131 Mont Saint-Aignan, France |
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| Abstract: | Starting from commercial chlorodiazines, we report the synthesis of pyridin-2-yldiazines. The first lithiation and functionalization of these compounds are reported and the regioselectivity of the metallation is discussed. The functionalization via the metallation reaction, provides a new access to substituted pyridin-2-yldiazines, which could be used as building blocks in supramolecules. |
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| Keywords: | Pyridin-2-yldiazines Metallation Functionalization ortho-directing group |
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