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Palladium-catalyzed carbene insertion into benzyl bromides
Authors:Kevin L. Greenman
Affiliation:Department of Chemistry, University of California, Irvine, CA 92697, USA
Abstract:Palladium can catalyze the insertion of ethyl diazoacetate into benzyl bromides. The key step in the catalytic cycle is the migratory insertion of a carbene, derived from ethyl diazoacetate, into a Pd-C bond.
Keywords:Palladium   Carbene   Stoichiometric insertion
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