Nickel-catalyzed couplings and cyclizations involving allenes, aldehydes, and organozincs |
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Authors: | Minsoo Song |
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Affiliation: | Department of Chemistry, Wayne State University, Detroit, MI 48202, USA |
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Abstract: | Cyclizations of allenyl aldehydes and intermolecular couplings of allenes and aldehydes provide a direct procedure for the preparation of homoallylic alcohols. The couplings and cyclizations involve the use of diorganozinc reagents as reducing agents and Ni(COD)2 as the catalyst. |
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Keywords: | Cyclizations Couplings π-System |
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