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Reversal of aryl bromide reactivity in Pd-catalysed aryl amination reactions promoted by a hemilabile aminophosphine ligand |
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| Authors: | Sebastien L Parisel Adriana Amoedo Pereira José M Vila |
| Institution: | a Department of Chemistry, King's College London, Strand, London WC2R 2LS, UK b Departamento de Química Inorgánica, Facultad de Química, Universidad de Santiago e Compostela, E-15782, Spain c Department of Chemistry, Imperial College London, Exhibition Road, South Kensington, London SW7 2AZ, UK |
| Abstract: | Incorporation of a hemilabile amino group with a bulky, electron-rich phosphorus ligand led to a reversal in the order of aryl bromide reactivity in Pd-catalysed aryl amination reactions. |
| Keywords: | Palladium catalysis PN ligands Aryl amination Aryl bromides |
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