Rigorous modelling and optimization of hybrid separation processes based on pervaporation |
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Authors: | Katalin Koczka Peter Mizsey Zsolt Fonyo |
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Institution: | (1) Department of Chemical and Environmental Process Engineering, Research Group of Technical Chemistry, Hungarian Academy of Sciences, Budapest University of Technology and Economics, Budapest, H-1521, Muegyetem rkp 3, Hungary |
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Abstract: | Hybrid separation processes are becoming more and more important in the practice if membrane technologies are also involved.
In this work, a systematic investigation is completed for three sequence alternatives of distillation and pervaporation. These
are the following: pervaporation followed with distillation (PV+D), distillation followed with pervaporation (D+PV), two distillation
columns and a pervaporation unit between them (D+PV+D). The hybrid separation process alternatives are evaluated with rigorous
modelling tools, but first, a rigorous simulation algorithm is determined for the pervaporation. The three hybrid separation
processes are rigorously modelled with CHEMCAD, and optimized with the dynamic programming optimization method for the case
of the separation of ethanol-water mixture. The objective function is the total annual cost (TAC). The energy consumption
is also investigated. The selection of the ethanol-water mixture has two motivations: (i) it is quite often studied and well
known, and (ii) to make biofuel (ethanol) production more economical, membrane technologies might also be applied. The results
are compared with each other and with the classical separation completed with heteroazeotropic distillation. The optimized
TAC shows that the distillation column followed with pervaporation is the most economical hybrid separation process alternative.
Its TAC is about 66% of that of the classical separation.
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Keywords: | hybrid separation processes CHEMCAD |
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