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Self-association and complexation of triterpene glycosides and cholesterol |
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| Authors: | L. A. Yakovishin N. I. Borisenko M. I. Rudnev E. V. Vetrova V. I. Grishkovets |
| Affiliation: | (1) Sevastopol’ National Technical University, 99053 Sevastopol, Ukraine;(2) Ecology-Analytical Center, South Federal University, 344090 Rostov-on-Don, Russia;(3) Institute of Physical and Organic Chemistry, South Federal University, 344090 Rostov-on-Don, Russia;(4) Vernadskii Taurida National University, 95007 Simferopol’, Ukraine |
| Abstract: | Self-association of hederagenin 3-O-α-L-rhamnopyranosyl-(1→2)-O-α-L-arabinopyranoside (α-hederin) and its 28-O-α-L-rhamnopyranosyl-(1→4)-O-β-D-glucopyranosyl-(1→6)-O-β-D-glucopyranosyl ether (hederacoside C) with cholesterol was studied using mass spectrometry (ESI MS). Possible complexation of the glycosides with cholesterol was examined. The ichtyotoxic activity of the glycosides and their mixtures with cholesterol to Barbus fefrozona was studied. |
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