| Synthesis,Crystal Structure,and Topology Analysis of One Novel Interpenetrated 2D Cobalt Coordination Polymer, {[Co(HTCB)(4,4'-btb)]·H_2O}_n |
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| 引用本文： | 高艳,范黎明,宋维阔,刘新征,张修堂.Synthesis,Crystal Structure,and Topology Analysis of One Novel Interpenetrated 2D Cobalt Coordination Polymer, {[Co(HTCB)(4,4'-btb)]·H_2O}_n[J].结构化学,2014,33(9):1333-1338. |
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| 作者姓名： | 高艳 范黎明 宋维阔 刘新征 张修堂 |
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| 作者单位： | [1]Advanced Material Institute of Research, College of Chemistry andChemical Engineering, Qilu Normal University, Jinan 250013, China; [2]State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100, China |
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| 基金项目： | supported by the National Natural Science Foundation of China(20873150);the Natural Science Foundation of Shandong Province(ZR2010BQ023) |
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| 摘 要： | One novel cobalt coordination polymer, {Co(HTCB)(4,4'-btb)]·H2O}n(1, H3TCB= 1,3,5-tris(4-carboxyphenyl)benzene, 4,4'-btb = 4,4'-bis(1,2,4-triazol-3-yl)biphenyl), has been synthesized and characterized by elemental analysis, IR, powder X-ray diffraction(PXRD), and thermogravimetric(TG) analyses. X-ray diffraction analysis reveals that complex 1 is a 2D 2-fold interpenetrated {44,62}-sql Co(HTCB)(4,4'-btb)] sheet based on the 1D Co(HTCB)]n chains and1 D Co(4,4'-btb)]n chains. The crystal of 1 crystallizes in triclinic, space group P 1 with a =9.529(12), b = 13.914(16), c = 14.906(17), V = 1903(4) 3, Z = 2, C45H34N6CoO7, Mr = 829.71,Dc = 1.448 g/cm3, F(000) = 858 and μ(MoKα) = 0.514 mm-1. The final R = 0.0655 and wR = 0.1136 for 6603 observed reflections with I 2σ(I) and R = 0.1136 and wR = 0.1747 for all data.
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| 关 键 词： | 配位聚合物 BTB 拓扑分析 晶体结构 2D 合成 H2O 粉末X射线衍射 |
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